Selecting Loading Capacitor Values for 32 kHz Crystal

Most likely the 22pF values used by TI are a compromise (cost / availability). The crystal can generally tolerate a few pF plus or minus the calculated value. I would guess that some empirical testing went into the decision to use 22pF instead of a closer value, or perhaps 22pF was already on the BOM.

Ultimately, even a calculation like what's in the datasheet is based on stray capacitance 'guesstimation'. You have to test whatever capacitor value you come up with and make sure that it works in your end product.

Also, page 20 of the C1111 datasheet that you linked to says 12-18pF is the range to use for the 32.768kHz crystal. Your mileage may vary.

The most important thing to keep in mind is that the capacitor should be tight tolerance with an appropriate dielectric material (one that isn't highly temperature dependent, such as NP0/C0G).

Further reading: here's a link to a good explanation of the topic of how crystals and capacitors interact.