WPF Popup : open with animation

Popup will animate if you have set AllowsTransparency true. like -

AllowsTransparency="True".

From MSDN

A Popup can only animate when the AllowsTransparency property is set to true. This requires the application that creates the Popup control to run with full trust. If the PlacementTarget is animated, the Popup will not be animated.

XAML should look like

<DockPanel  Width="500" Background="Aqua">
  <Popup Placement="Center" PlacementRectangle="0,0,30,50"  
          IsOpen ="True" AllowsTransparency="True"
          PopupAnimation="Fade">
    <TextBlock Background="Purple">Popup Text</TextBlock>
  </Popup>
</DockPanel>

And you can read more here.