Sleeping SPID blocking other transactions

Use the most_recent_sql_handle in sys.dm_exec_connections to see the last statement that was executed.

SELECT  t.text,
        QUOTENAME(OBJECT_SCHEMA_NAME(t.objectid, t.dbid)) + '.'
        + QUOTENAME(OBJECT_NAME(t.objectid, t.dbid)) proc_name,
        c.connect_time,
        s.last_request_start_time,
        s.last_request_end_time,
        s.status
FROM    sys.dm_exec_connections c
JOIN    sys.dm_exec_sessions s
        ON c.session_id = s.session_id
CROSS APPLY sys.dm_exec_sql_text(c.most_recent_sql_handle) t
WHERE   c.session_id = 72;--your blocking spid

Also check if there is an open transactions for that spid

SELECT  st.transaction_id,
        at.name,
        at.transaction_begin_time,
        at.transaction_state,
        at.transaction_status
FROM    sys.dm_tran_session_transactions st
JOIN    sys.dm_tran_active_transactions at
        ON st.transaction_id = at.transaction_id
WHERE   st.session_id = 72;--your blocking spid

From comments, I'm guessing you had a client side Command timeout that has aborted the SQL query. This does not rollback the transaction because the connection stays open on SQL Server due to connection pooling.

So, you need to use SET XACT_ABORT ON or add some client rollback code

See SQL Server Transaction Timeout for all the gory details

Have you tried using Adam Machanic's sp_whoisactive? There's an option to get the outer command to see if it really is within a proc. It could be the application is holding open a transaction instead of committing it. Try looking at DBCC OPENTRAN as well.