Quasiclassical QM for centrally symmetric fields

I) Let us for simplicity put the physical constants $\hbar=1=m$ to one. OP is considering the usual transcription $u(r)\equiv rR(r)$ of the 3D radial TISE into a 1D TISE,

$$\tag{A} - \frac{1}{2} u^{\prime\prime}(r)+U_{\ell}(r)u(r) ~=~E u(r),$$

where the total potential energy

$$\tag{49.8b} U_{\ell}(r)~:=~ U(r) + \frac{C_{\ell}}{2r^2} $$

is a sum of a central potential energy $U(r)$ and a centrifugal potential energy $\frac{C_{\ell}}{2r^2}$. Here and below the equation numbers refer to Ref. 1. The constant

$$\tag{B} C_{\ell}~:=~\ell (\ell +1)~=~\left(\ell+\frac{1}{2}\right)^2 -\frac{1}{4} $$

in eq. (49.8b) is the eigenvalue of the $\hat{L}^2$ operator.

II) We are investigating a bound state where the angular momentum $\ell>0$ is non-zero.

We are interested in the situation where the centrifugal potential energy numerically completely dominates [and the potential $U(r)$ can be ignored] in a neighborhood $[0,r_0+\epsilon[$ of the classically forbidden interval $[0,r_0[$, where $r_0$ denotes the inner radial turning point. In other words,

$$\tag{C} E~\approx~\frac{C_{\ell}}{2r_0^2}. $$

We also want the semiclassical WKB approximation to be valid in the interval $[0,r_0[$ (away from the turning point). The semiclassical condition

$$\tag{46.6} |\lambda^{\prime}(r)|~\ll~ 1$$ implies that

$$\tag{D} \ell ~\gg~ 1.$$

III) The (absolute value of the) momentum is

$$\tag{46.5} p(r)~:=~\sqrt{2\left|E - U_{\ell}(r)\right|} ~\approx~\sqrt{C_{\ell}\left|r^{ - 2} - r_0^{-2}\right|} \quad\text{for}\quad r\in[0,r_0+\epsilon[,$$

where

$$\tag{E} \sqrt{C_{\ell}} ~\stackrel{(B)}{=}~\ell+\frac{1}{2}-\frac{1}{8\ell}+{\cal O}(\ell^{-2}). $$

The semiclassical connection formulas yield

$$\tag{F} u(r)~\approx~\frac{c}{\sqrt{p(r)}}\exp\left[ \int_{r}^{r_0} \! dr^{\prime}~p(r^{\prime})\right] \quad\text{for}\quad r~<~ r_0, $$

$$\tag{48.1} u(r)~\approx~\frac{c}{\sqrt{p(r)}}\cos\left[ \int_{r_0}^{r} \! dr^{\prime}~p(r^{\prime})-\frac{\pi}{4}\right]$$ $$~=~\frac{c}{\sqrt{p(r)}}\sin\left[ \int_{r_0}^{r} \! dr^{\prime}~p(r^{\prime})+\frac{\pi}{4}\right] \quad\text{for}\quad r~>~ r_0, $$

where $c\in\mathbb{C}$.

IV) The semiclassical approximation (F) behaves as

$$\tag{G} u(r)~\propto~ r^{\sqrt{C_{\ell}}+\frac{1}{2}}\quad\text{for}\quad r~\to~ 0^{+}, $$

while the well-known exact behavior is

$$\tag{32.15} u(r)~\propto~ r^{\ell+1}\quad\text{for}\quad r~\to~ 0^{+}. $$

Hence, the semiclassical approximation would have the correct behavior at the origin $r=0$ if we replace (E) with $\ell+\frac{1}{2}$.

V) Alternatively, in the free case $U(r)=0$, the semiclassical approximation (48.1) behaves as$^1$

$$\tag{H} u(r)~\propto~\sin\left[\sqrt{C_{\ell}}\left(\frac{r}{r_0}-\frac{\pi}{2}\right)+\frac{\pi}{4}\right] \quad\text{for}\quad r~\to~\infty, $$

while the well-known exact behavior is

$$\tag{33.12} u(r)~\propto~\sin\left[\sqrt{C_{\ell}}\frac{r}{r_0}-\ell\frac{\pi}{2}\right] \quad\text{for}\quad r~\to~\infty. $$

This again suggests to replace (E) with $\ell+\frac{1}{2}$.

References:

  1. L.D. Landau & E.M. Lifshitz, QM, Vol. 3, 3rd ed, 1981; $\S49$.

$^1$ Momentum integral becomes

$$ \frac{1}{\sqrt{C_{\ell}}} \int_{r_0}^{r} \! dr^{\prime}~p(r^{\prime}) ~=~\int_1^{\frac{r}{r_0}} \! \frac{dx}{x}\sqrt{x^2-1} ~=~\left[ \sqrt{x^2-1}+\arctan\frac{1}{\sqrt{x^2-1}} \right]_{x=1}^{x=\frac{r}{r_0}}$$ $$\tag{I} ~\approx~\frac{r}{r_0}-\frac{\pi}{2}\quad\text{for}\quad r~\to~\infty. $$