Pandas: Adding a df column based on other column with multiple values map to the same new column value

Build your dict then do map

d={'dog':'ani','cat':'ani','green':'color','blue':'color'}
df1['col2']=df1.col1.map(d)
df1
    col1   col2
0    cat    ani
1    cat    ani
2    dog    ani
3  green  color
4   blue  color

Since multiple items may belong to a single category I suggest you start with a dictionary mapping category to items:

cat_item = {'animal': ['cat', 'dog'], 'color': ['green', 'blue']}

You'll probably find this easier to maintain. Then reverse your dictionary using a dictionary comprehension, followed by pd.Series.map:

item_cat = {w: k for k, v in cat_item.items() for w in v}

df1['col2'] = df1['col1'].map(item_cat)

print(df1)

    col1    col2
0    cat  animal
1    cat  animal
2    dog  animal
3  green   color
4   blue   color

You can also use pd.Series.replace, but this will be generally less efficient.