Jump to first non-whitespace character in line in emacs

The command is back-to-indentation, bound by default to M-m.

This is what I picked up from a previous Stack Overflow question:

(defun smart-beginning-of-line ()
  "Move point to first non-whitespace character or beginning-of-line.

Move point to the first non-whitespace character on this line.
If point was already at that position, move point to beginning of line."
  (interactive)
  (let ((oldpos (point)))
    (back-to-indentation)
    (and (= oldpos (point))
         (beginning-of-line))))
(global-set-key [home] 'smart-beginning-of-line)
(global-set-key "\C-a" 'smart-beginning-of-line)