How to make VMWare Workstation use multiple windows for VMs instead of tabbed display?

Execute another window from VMware main menu: File -> New Window

A link to VMware community discussion on the same issue

Just drag the tab out of the VMWare window and take it to the other monitor. If that's what you mean. It will create a new solitary window with the other running OS in it. Have done that on Ubuntu, and it should work the same for Windows 7.

NOTE: the dragging action only works if the VMware window is not in full screen mode.

Use Remote Desktop (MSTSC in Win 7) and display each as a window.

goto> Start > search box type MSTSC. Enter your guest IP address into the address:

You may have to enable remote client access on your guest. Here is a good article from 4sysops.com