General relativity: For massless particles, is the momentum and velocity 4-vectors equal?

1. How should we define momentum of a massless point particle? It seems most systematic to use the Lagrangian formalism. The Lagrangian of a massive or massless point particle is$^1$ $$ L~=~\frac{\dot{x}^2}{2e}-\frac{m^2e}{2}, \qquad \dot{x}^2~:=~g_{\mu\nu}(x)~ \dot{x}^{\mu}\dot{x}^{\nu}~<~0, \qquad \dot{x}^{\mu}~:=\frac{dx^{\mu}}{d\lambda} ,\tag{1}$$ cf. e.g. this, this and this Phys.SE posts. We now restrict to the massless case $$ m~=~0. \tag{2}$$

2. In eq. (1) $\lambda$ is a worldline (WL) parameter, and $e>0$ is a WL einbein field introduced to make the action $$S[x,e]~=~ \int\! \mathrm{d}\lambda ~L\tag{3}$$ gauge invariant under WL reparamerizations $$ \lambda\longrightarrow \lambda^{\prime}~=~f(\lambda).\tag{4} $$ In more detail the WL einbein field $e$ transforms as a WL co-vector/one-form, $$ e~\mathrm{d}\lambda~=~e^{\prime}~ \mathrm{d}\lambda^{\prime}.\tag{5} $$

3. We can now address OP's question. The Lagrangian $4$-momentum$^2$ is defined in the standard way: $$ p_{\mu}~:=~\frac{\partial L}{\partial \dot{x}^{\mu}}~\stackrel{(1)}{=}~ \frac{1}{e}g_{\mu\nu}(x)~\dot{x}^{\nu}.\tag{6}$$

4. Carroll's eq. (3.62), which in our notation reads$^3$ $$p^{\mu}~=~\dot{x}^{\mu}, \tag{7}$$ is eq. (6) in the gauge $e=1$, cf. e.g. this Phys.SE post.

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$^1$ In this answer we put the speed of light $c=1$ to one and use the sign convention $(−,+,+,+)$.

$^2$ It is fun to check that in the massive case the Lagrangian momentum (6) becomes the standard $4$-momentum $$ p^{\mu}~\approx~\frac{m\dot{x}^{\mu}}{\sqrt{-\dot{x}^2}}\tag{8}$$ in the static gauge $\lambda=x^0$ in Minkowski space. [Here the $\approx$ symbol means equality modulo eom.]

$^3$ Note that the notion of $4$-velocity $$ u^{\mu}~:=~\frac{dx^{\mu}}{d\tau} \tag{9} $$ is not defined for massless particles. Here $\tau$ denotes proper time, which doesn't change for a massless particle. So OP's equation $p^{\mu}=u^{\mu}$ does not make sense if $u^{\mu}$ is supposed to be the conventional 4-velocity.