Fundamentally, why do some nuclei emit ionizing radiation?

All elements above Iron are created when a star implodes under its own gravity in the form of a supernova. These heavy elements are ejected into space in this process and go on to form parts of planets such as Earth. This includes all their various radioactive isotopes.

From the moment the unstable isotope is created, it wants to radioactively decay so as to attain a more stable configuration. This will continue to happen until the atom reaches a state which has an extremely long half life (such as $\text{Pb}^{82}$). The three most important ways in which an atom can decay are as follows-

1) $\alpha$-Decay: Ejection of Helium$(\text{He}^{2+})$ ion

2) $\beta^-$-Decay: Ejection of electron$(\text{e}^{-}) \text{ and anti-neutrino}(\bar v_e)$

3) $\beta^+$-Decay: Ejection of positron$(\text{e}^{+}) \text{ and neutrino} (v_e)$

These three affect the atomic and mass number in different ways which you can read more about here. All radioactive disintegration follows first order kinetics. The $\gamma$-rays released is just the difference in mass between the two atoms. This happens according to Einstein's famous equation $E=\Delta mc^2$. These are just the basics which should be sufficient for understanding purposes.


About the basic theoretical framework:
To an acceptable approximation the total internal energy of the nucleus can be thought of as arising from two forces: the strong nuclear force and the electrostatic force.

The protons in the nucleus all repel each other as they are all positively charged; it's the strong nuclear force that holds the nucleus together. The range of the strong nuclear force is limited. For a large nucleus the strong nuclear force does not extend from one side of the nucleus to another. This is why for nuclei heavier than the nuclei of lead there is no stable isotope.

The wikipedia article about radio-active decay also has the diagram with the table of isotopes

For the lightest elements there is a matching number of neutrons and protons in the nucleus. The higher the atomic number the more neutrons there are in proportion to the protons. The neutrons contribute to the total amount of strong nuclear force holding the nucleus together, but not to electrostatic force, thus supporting stability of the nucleus.

For each atomic number there is an optimum ratio of neutrons to protons. For an isotope with that optimum ratio there is no decay mode available: all states that can be reached through any of the decay modes is a higher energy state than the one that that nucleus is already in.

There is a very interesting video about nuclear decay by the science youtuber Scott Manley. (The target audience is novices, with Scott frequenty giving the "This is of course a gross oversimplification." warning.)

The natural question is: well, if a decay mode is available, why do many isotopes have such a long half life?

Scott Manley gives one example where the only available decay mode requires two beta decays happening simultaneously (or at least within a sufficiently short time window). That makes for a much smaller probability for that decay to occur.

Any radio-active decay has to overcome an energy hump. The usual imagery is one of a marble on a ledge with a rim, next to a long steep hillside. If the marble can make it over the rim it can roll all the way down, but first the marble has to make it over that rim.

For the nucleus of an isotope with a long half life: given enough time at some point in time some part of the nucleus will happen to have the energy to make it over the hump. The probability of making it over the hump is never zero, but the higher the initial hump the smaller the probability.

Acknowledgng the comment by PM 2ring I have scratched out the above two paragraphs. Wrong picture, even when allowing for gross oversimplification.

New attempt: decay mode is not a single process, but a complex process. There is enough intricacy such that depending on specific circumstances the probability of a decay occuring at all can be very low.


I want to correct your question: you said that $\alpha$ and $\beta$ radiation are "observable" inside the nucleus. If I understood you correctly, you mean that before decaying these particles were a part of the nucleus. For $\alpha$ particles it is correct but not at all for $\beta$:

The nucleus is made out of protons and neutrons, meaning only from quarks (the particles that make them), while a beta particle is an electron or a positron, which isn't a quark (technically, it is a type of lepton). Meaning the beta particle couldn't be observed in the nucleus before the decay because it wasn't there in the first place!

To understand what is going on, you need to understand the nature of $\beta$ decay (which is called "the weak force"). It is quite complex, but as a beginning, you should know about 2 important quarks: the up quark (let's call it 'u') and the down quarks ('d'). The u quark has an electric charge of $+\frac{2}{3} e$ and the d quark has a charge of $-\frac13 e$ (where $-e$ is the charge of an electron, and $e$ is the charge of the proton). A proton is just 2 up quarks and one down quark, so the total charge is $\frac23 e + \frac23 e - \frac13 e = e$, and a neutron is one up quark and 2 down quarks, so the total charge is $\frac23 e -\frac13 e - \frac13 e=0$ (neutral particle).

In beta decay, an up quark becomes a down quark or viceversa (which "converts" a proton: uud , to a neutron: udd , or viceversa). Notice, however, that they have different electric charge. For conservation of charge, what in one moment a down quark "decides" to become an up quark, he will gain an electric charge of $e$ (going from $-\frac13 e $ to $\frac23 e$), meaning something else with a charge of $-e$ needs to be created in order of that to happen: the electron! Meaning there was no electron at all first (the quarks are elementary particles, they don't consist of electrons) and at the moment of decay the beta particle was born. The beta particle couldn't be observed before the decay because it didn't exist yet.

This answer doesn't answer your question, but it is too long for a comment and I think it was worth discussion. I hope it helped a bit to understand more.