Can I force jQuery.css("backgroundColor") returns on hexadecimal format?

Colors are always returned as rgb (except IE6 which already returns in hex), then we cannot return in another format natively.

Like you said, you can write a function to convert hex to rgb. Here is a topic with several examples of how to write this function: How to get hex color value rather than RGB value?.

But you wonder if there is a way to directly return the jQuery already in hex: the answer is yes, this is possible using CSS Hooks since jQuery 1.4.3.

The code should be:

$.cssHooks.backgroundColor = {
    get: function(elem) {
        if (elem.currentStyle)
            var bg = elem.currentStyle["backgroundColor"];
        else if (window.getComputedStyle)
            var bg = document.defaultView.getComputedStyle(elem,
                null).getPropertyValue("background-color");
        if (bg.search("rgb") == -1)
            return bg;
        else {
            bg = bg.match(/^rgb\((\d+),\s*(\d+),\s*(\d+)\)$/);
            function hex(x) {
                return ("0" + parseInt(x).toString(16)).slice(-2);
            }
            return "#" + hex(bg[1]) + hex(bg[2]) + hex(bg[3]);
        }
    }
}

And when you call $(".highlighted").css("backgroundColor"), the return will be #f0ff05. Here is a working sample to you see it working.