Can I access variables from another file?

You can export the variable from first file using export.

//first.js
const colorCode = {
    black: "#000",
    white: "#fff"
};
export { colorCode };

Then, import the variable in second file using import.

//second.js
import { colorCode } from './first.js'

export - MDN

As Fermin said, a variable in the global scope should be accessible to all scripts loaded after it is declared. You could also use a property of window or (in the global scope) this to get the same effect.

// first.js
var colorCodes = {
  back  : "#fff",
  front : "#888",
  side  : "#369"
};

... in another file ...

// second.js
alert(colorCodes.back); // alerts `#fff`

... in your html file ...

<script type="text/javascript" src="first.js"></script> 
<script type="text/javascript" src="second.js"></script>